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General Information
- General Information
  - General Information Data Description
    - AJCSD_ID C004-720-20A CAS RN 124-09-4
      
      Chemical Substance Name Hexane-1,6-diyldiamine
      
      Molecular Formula C6H16N2
      
      Molecular Weight 116
      
      SMILES NCCCCCCN
      
      Structure
- Synonym
  - Synonym Data Description
    - Synonym 1,6-Diaminohexane
      
      1,6-Hexanediamine
      
      Hexamethylenediamine
      
      Hexane-1,6-diamine
      
      HMD(A)

Laws and Regulations

Japan

Act on the Evaluation of Chemical Substances and Regulation of Their Manufacture, etc. (Chemical Substances Control Law ; CSCL)

Japan CSCL: Existing Chemical Substances Data Description Definition of the terms of Section 6 [PDF] Definition of the terms of Section 7 [PDF] Import Clearance Procedures[PDF] Notification of the Manufacturing Amount, etc[PDF]

MITI Number	2-153	Category	Section 2
Chemical Substance Name	Hexamethylenediamine
Remarks	-
Details	to J-CHECK
Remarks to Existing Chemical Substances of Industrial Safety and Health Act	Chemicals have been notified in accordance with the provisions of Chemical Substances Control Law by June 29, 1979
Details to Existing Chemical Substances of Industrial Safety and Health Act	to MHLW site (in Japanese)

Japan CSCL: Type II Monitoring Chemical Substances (before amendment) Data Description Import Clearance Procedures[PDF] Notification of the Manufacturing Amount, etc[PDF]
- Registration Number
  1019
  Date of Designation in the Official Gazette 2010/04/01
  
  MITI Number
  2-153
  
  Chemical Substance Name Hexamethylenediamine
  
  Remarks -
  
  Details to J-CHECK

Act on Confirmation, etc. of Release Amounts of Specific Chemical Substances in the Environment and Promotion of Improvements to the Management Thereof(PRTR-SDS Law)
- Japan: PRTR-SDS Law (until March 2023) Data Description Outline PRTR Law (METI site) Analysis of PRTR data
  - Classification I Cabinet Order Number
    1-390
    
    Cabinet Order Name Hexamethylenediamine
    
    Remarks -
    
    Basis of selection Hazard Data (in Japanese)
- Japan: PRTR-SDS Law (from April 2023) Data Description Outline PRTR Law (METI site)
  - JPSN(Japan PRTR-SDS Number)
    390
    Classification I Cabinet Order Number 1-434
    
    Cabinet Order Name Hexamethylenediamine
    
    Remarks -
    
    Basis of selection Hazard Data (in Japanese)

Industrial Safety and Health Act (ISHA)

Japan ISHA: Chemical Substances Requiring Labeling and Delivery of Documents, etc. Data Description GHS compatible model label creation method (MH LW site : in Japanese) Risk assessment implementation support tool (MHLW site : in Japanese) Target substances list (MHLW site: in Japanese) Responsibilities of Business Operators (JNIOSH site: in Japanese)

Cabinet Order Number	Attached table 2-1859 of Ordinance	Implementation	Effective April 1, 2025
Cabinet Order Name	Hexamethylenediamine
Range of Application for Label (weight%)	>=1
Range of Application for SDS (weight%)	>=0.1

Japan ISHA: Chemical substances that cause skin disorders, etc. and other chemical substances that must be handled with impermeable protective equipment etc. based on special chemical regulations. Data Description Target substances list, etc.(MHLW site: in japanese) Responsibilities of Business Operators (JNIOSH site: in Japanese)
- Substance Name Hexamethylenediamine
  
  Classification of Target Substances Skin Irritating Hazardous Substances Cutoff value(weight %) 1
  
  Implementation 2024/04/01
  
  Details to the GHS Classification

Poisonous and Deleterious Substances Control Act
- Japan Poisonous and Deleterious Substances Control Act Data Description Link to the Act (MOJ site)
  - Classification Deleterious Substances(Cabinet order) Law or Cabinet Order Number
    Article 2-1-91-4 of Cabinet order
    
    Law or Cabinet Order Name Hexane-1,6-diamine and preparations containing it

Air Pollution Control Act
- Japan Air Pollution Control Law Data Description Air & Transportation (MOE site)
  - Classification Substances that may be classified as Hazardous Air Pollutants Cabinet Order Number
    205 of Central Environment Council 9th Report (Appendix 1)
    
    Cabinet Order Name Hexamethylenediamine

Food Sanitation Act

Food Sanitation Act: Table 1 (1) in Appended table 1 of Specifications and Standards Notification; Base polymers (Plastics) Data Description The positive list system for food utensils, containers and packaging (MHLW)

Category	17. Cross-linking epoxypolymer
Number Name	1. Copolymer composed of one or more epoxypolymers(A.-H.) with polyamides(I.) or (J.) and/or cross-linking agents(K.); Polyamide; I. Polyamides composed of one or more acids (I-1.), one or more amines (I-2.) and one or more modifiers (I-3.); I-2. Amine; 7)hexamethylenediamine
Food category (Ac\|Fa\|Mi\|Al\|Ot)	○\|○\|○\|○\|○	Max. Temp./Synth. Resin Gr.	III/1

Food Sanitation Act: Table 1 (2) in Appended table 1 of Specifications and Standards Notification; Base polymers (Coatings) Data Description The positive list system for food utensils, containers and packaging (MHLW)

Category	6. Polyamide
Number Name	1. Copolymer composed of acid(A.),amine (B.) and modifier (C.); B. Amine; 7)hexamethylenediamine
Food category (Ac\|Fa\|Mi\|Al\|Ot)	○\|○\|○\|○\|○	Max. Temp./Synth. Resin Gr.	III/1

Category	7. Polyurethane
Number Name	1. Copolymer of isocyanates(A.) with following one or more substances(B.)-(F.) or modifiers(G.); C. Amine; 19)hexamethylenediamine
Food category (Ac\|Fa\|Mi\|Al\|Ot)	○\|○\|○\|○\|○	Max. Temp./Synth. Resin Gr.	III/1,3

Food Sanitation Act: Table 1 (3) in Appended table 1 of Specifications and Standards Notification; Base polymers (Trace amount monomer) Data Description The positive list system for food utensils, containers and packaging (MHLW)
- Number Name 10. Organic nitrogen compound; 23)hexamethylenediamine

Food Sanitation Act: Table 1 in Appended table 1 of Revised Positive List of Food Apparatus and Containers, Packaging (Base materials)(From June 1, 2025) Data Description Revised Positive List of Food Apparatus and Containers, Packaging (CAA)

Substance Code	04-782	Polymer group	1
Base Materials	Cross-linking polymer of epoxy compound
Classification (Type, processing, etc.)	optional substance (including reaction products with essential monomers or epichlorohydrin)
Name	hexamethylenediamine
Requirements	Molecular weight of the part composed only of the optional substances (excluding reaction products with essential monomers or epichlorohydrin): Less than 1,000

Substance Code	10-758	Polymer group	1
Base Materials	Polymer with ion exchange ability and/or adsorption ability
Classification (Type, processing, etc.)	optional substance
Name	hexamethylenediamine
Requirements	Molecular weight of the part composed only of optional substance: Less than 1,000

Substance Code	17-126	Polymer group	3
Base Materials	Polymer mainly composed of amide link (including polymer composed of aziridine or 2-ethyl-2-oxazoline as the main monomer)
Classification (Type, processing, etc.)	essential monomer ; amine
Name	hexamethylenediamine
Requirements	The sum of amines and acids: Not less than 50% of the polymer components

Substance Code	21-4230	Polymer group	4 or 5
Base Materials	Polymer used for coating that involves chemical reaction during film formation
Classification (Type, processing, etc.)	organic compound ; organonitrogen compound
Name	hexamethylenediamine

Malaysia
- Use and Standards of Exposure of Chemicals Hazardous to Health (USECHH) Regulation 2000
  - Malaysia: Use and Standards of Exposure of Chemicals Hazardous to Health (USECHH) Regulation 2000 Data Description
    - Category Schedule I
      
      Substance name in English 1,6-Hexanediamine
      
      Substance name in local language -

Philippines
- Toxic Substances and Hazardous and Nuclear Wastes Control Act
  - the Philippines: Toxic Substances and Hazardous and Nuclear Wastes Control Act (RA6969) Data Description
    - Category PICCS
      
      Substance name in English 1,6-Diaminohexane
      
      Substance name in local language -
      
      Related Decree -
      
      Category PICCS
      
      Substance name in English 1,6-Hexanediamine
      
      Substance name in local language -
      
      Related Decree -
      
      Category PICCS
      
      Substance name in English HEXAMETHYLENE DIAMINE
      
      Substance name in local language -
      
      Related Decree -
      
      Category PICCS
      
      Substance name in English HEXAMETHYLENEDIAMINE
      
      Substance name in local language -
      
      Related Decree -
      
      Category PICCS
      
      Substance name in English HEXANE-1,6-DIAMINE
      
      Substance name in local language -
      
      Related Decree -

Vietnam
- Law on Chemical / Luật hóa chất số 06/2007/QH12 ngày 21 tháng 11 năm 2007
  - Viet Nam:Law on Chemical:Decree 113/2017/ND-CP:List of chemicals subject to conditional industrial production and trading Data Description Law on Chemical Decree 113/2017/ND-CP Circular 32/2017/TT-BCT National Chemical Database System
    - Substance name in English Hexa methylene diamine
      
      Substance name in local language -
  - Viet Nam:Law on Chemical:Decree 113/2017/ND-CP:List of chemicals subject to compulsory declaration Data Description Law on Chemical Decree 113/2017/ND-CP Circular 32/2017/TT-BCT National Chemical Database System
    - Substance name in English Hexamethylene diamine
      
      Substance name in local language -

World Customs Organization

International Convention on the Commodity Description and Coding Systems (HS Convention)

HS Code: Section VI “Products of the Chemical or Allied Industries" Data Description

Chapter	29	Chapter name	Organic chemicals
Heading	2921	Substance name (Heading)	Amine-function compounds
HS Code	2921.22	Substance Name	Acyclic polyamines and their derivatives; salts thereof : Hexamethylenediamine and its salts

Chemical Hazard and Risk Information

Japan

GHS Classification Results by the Japanese Government
- NITE Japan-GHS Data Description GHS information
  - Edition version_1
    
    Chemical Substance Name Hexamethylenediamine
    
    Classification Result To the result webpage To the Excel flie
- GHS Classification Results by the Japanese Government Data Description GHS Information
  - Year of implementation /renewal 2006 ID 189_H18_new
    
    Chemical Substance Name Hexamethylenediamine
    
    Classification Result To the resut webpage To the Excel flie
    
    Year of implementation /renewal 2011 ID 23B5516
    
    Chemical Substance Name Hexamethylenediamine
    
    Classification Result To the resut webpage To the Excel flie

Chemical Substances Hazard Assessment Report / Initial Risk Assessment Report

Chemical Substances Hazard Assessment Report / Initial Risk Assessment Report Data Description Guidance for Initial Risk Assessment ver.1 (in Japanese) Guidance for Initial Risk Assessment ver.2 (in Japanese)

Report Number	No.117
Assessed Chemical Substance Name	Hexamethylenediamine
Details	Hazard Assessment Report (in Japanese)	Date of publication/ renewal	2007/03
	Details Initial Risk Assessment Report (in Japanese)	Date of publication/ renewal	2008/06
	Details Summary of Initial Risk Assessment Report	Date of publication/ renewal	2010/05

AJCSD_ID	C004-720-20A	CAS RN	124-09-4
Chemical Substance Name	Hexane-1,6-diyldiamine
Molecular Formula	C6H16N2
Molecular Weight	116
SMILES	NCCCCCCN
Structure

Synonym	1,6-Diaminohexane
	1,6-Hexanediamine
	Hexamethylenediamine
	Hexane-1,6-diamine
	HMD(A)

Registration Number	1019	Date of Designation in the Official Gazette	2010/04/01
MITI Number	2-153
Chemical Substance Name	Hexamethylenediamine
Remarks	-
Details	to J-CHECK

Classification	I	Cabinet Order Number	1-390
Cabinet Order Name	Hexamethylenediamine
Remarks	-
Basis of selection	Hazard Data (in Japanese)

JPSN(Japan PRTR-SDS Number)	390	Classification	I	Cabinet Order Number	1-434
Cabinet Order Name	Hexamethylenediamine
Remarks	-
Basis of selection	Hazard Data (in Japanese)

Substance Name	Hexamethylenediamine
Classification of Target Substances	Skin Irritating Hazardous Substances	Cutoff value(weight %)	1
Implementation	2024/04/01
Details	to the GHS Classification

Classification	Deleterious Substances(Cabinet order)	Law or Cabinet Order Number	Article 2-1-91-4 of Cabinet order
Law or Cabinet Order Name	Hexane-1,6-diamine and preparations containing it

Classification	Substances that may be classified as Hazardous Air Pollutants	Cabinet Order Number	205 of Central Environment Council 9th Report (Appendix 1)
Cabinet Order Name	Hexamethylenediamine

Category	Schedule I
Substance name in English	1,6-Hexanediamine
Substance name in local language	-

Category	PICCS
Substance name in English	1,6-Diaminohexane
Substance name in local language	-
Related Decree	-

Edition	version_1
Chemical Substance Name	Hexamethylenediamine
Classification Result	To the result webpage To the Excel flie

Year of implementation /renewal	2006	ID	189_H18_new
Chemical Substance Name	Hexamethylenediamine
Classification Result	To the resut webpage To the Excel flie

Year of implementation /renewal	2011	ID	23B5516
Chemical Substance Name	Hexamethylenediamine
Classification Result	To the resut webpage To the Excel flie

Substance name in English	Hexa methylene diamine
Substance name in local language	-

Substance name in English	Hexamethylene diamine
Substance name in local language	-