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General Information

General Information Data Description

AJCSD_ID	C004-794-63A	CAS RN	78-67-1
Chemical Substance Name	2,2'-Dimethyl-2,2'-diazenediyldipropanenitrile
Molecular Formula	C8H12N4
Molecular Weight	164
SMILES	N#CC(C)(N=NC(C)(C#N)C)C
Structure

Synonym
- Synonym Data Description
  - Synonym 2,2'-Azobis(2-methylpropanenitrile)
    
    2,2'-Azobisisobutyronitrile

Notes on CAS RN
- Notes on CAS RN Data Description
  - Notes The CAS RN before replacement had been CAS RN 95210-41-6.

Laws and Regulations

Japan

Act on the Evaluation of Chemical Substances and Regulation of Their Manufacture, etc. (Chemical Substances Control Law ; CSCL)

Japan CSCL: Existing Chemical Substances Data Description Definition of the terms of Section 6 [PDF] Definition of the terms of Section 7 [PDF] Import Clearance Procedures[PDF] Notification of the Manufacturing Amount, etc[PDF]

MITI Number	2-1531	Category	Section 2
Chemical Substance Name	Azobisisobutyronitrile
Remarks	-
Details	to J-CHECK
Remarks to Existing Chemical Substances of Industrial Safety and Health Act	Chemicals have been notified in accordance with the provisions of Chemical Substances Control Law by June 29, 1979
Details to Existing Chemical Substances of Industrial Safety and Health Act	to MHLW site (in Japanese)

Japan CSCL: Type II Monitoring Chemical Substances (before amendment) Data Description Import Clearance Procedures[PDF] Notification of the Manufacturing Amount, etc[PDF]

Registration Number	701	Date of Designation in the Official Gazette	2003/09/29
MITI Number	2-1531
Chemical Substance Name	2,2'-Dimethyl-2,2'-diazenediylbis(propanenitrile) (synonym: 2,2'-Azobisbutyronitrile)
Remarks	-
Details	to J-CHECK

Act on Confirmation, etc. of Release Amounts of Specific Chemical Substances in the Environment and Promotion of Improvements to the Management Thereof(PRTR-SDS Law)
- Japan: PRTR-SDS Law (until March 2023) Data Description Outline PRTR Law (METI site) Analysis of PRTR data
  - Classification I Cabinet Order Number
    1-16
    
    Cabinet Order Name 2,2'-Azobisisobutyronitrile
    
    Remarks -
    
    Basis of selection Hazard Data (in Japanese)

Industrial Safety and Health Act (ISHA)

Japan ISHA: Chemical Substances Requiring Labeling and Delivery of Documents, etc. Data Description GHS compatible model label creation method (MH LW site : in Japanese) Risk assessment implementation support tool (MHLW site : in Japanese) Target substances list (MHLW site: in Japanese) Responsibilities of Business Operators (JNIOSH site: in Japanese)

Cabinet Order Number	Attached table 2-64 of Ordinance	Implementation	Effective April 1, 2025
Cabinet Order Name	2,2'-Azobisisobutyronitrile
Range of Application for Label (weight%)	>=1
Range of Application for SDS (weight%)	>=1

Poisonous and Deleterious Substances Control Act

Japan Poisonous and Deleterious Substances Control Act Data Description Link to the Act (MOJ site)

Classification	Deleterious Substances(Cabinet order)	Law or Cabinet Order Number	Article 2-1-32 of Cabinet order
Law or Cabinet Order Name	Organic cyanide compounds and preparations containing it. (except for the items listed as "excluded" in Article 2-1-32 of Cabinet order)

Water Pollution Prevention Act
- Japan Water Pollution Control Law Data Description Water / Soil / Ground Environment (MOE site)
  - Classification Harmful Substances Cabinet Order Number
    Article 2-2 of Cabinet order
    
    Cabinet Order Name Cyanide compounds
    
    Effluent Standards 1mg/L(CN)
    
    Purification Standards N.D.

Soil Contamination Countermeasures Act
- Japan Soil Contamination Countermeasures Act Data Description Water / Soil / Ground Environment (MOE site)
  - Classification Class 2 Cabinet Order Number
    Article 1-5 of Cabinet order
    
    Cabinet Order Name Cyanide compounds
    
    Soil Leachate Standard N.D.(CN)
    
    Soil Concentration Standard 50mg/kg(CN-)

Fire Service Act

Fire Service Act : Hazardous Materials Data Description

Number of cabinet order etc.	Article 2, Paragraph 7 of the Act, Appended Table 1, Category V (5)
Category; Property	Category V; Self-Reactive Substances
Item	Azo compounds
Property	Class 2 self-reactive substances
Designated quantity	100kg
Sources	Hazardous Materials Disaster Information Support System, Hazardous Materials Data Book 2nd edition, MHLW Website; Sample SDS, Encyclopedia of Hazardous Materials

Philippines
- Toxic Substances and Hazardous and Nuclear Wastes Control Act
  - the Philippines: Toxic Substances and Hazardous and Nuclear Wastes Control Act (RA6969) Data Description
    - Category PICCS
      
      Substance name in English 2,2'-AZOBIS(2-METHYL PROPANITRILE)
      
      Substance name in local language -
      
      Related Decree -
      
      Category PICCS
      
      Substance name in English AZOBIS-ISOBUTYRATE NITRILE
      
      Substance name in local language -
      
      Related Decree -
      
      Category PICCS
      
      Substance name in English AZOBIS-ISOBUTYRONITRILE
      
      Substance name in local language -
      
      Related Decree -
      
      Category PICCS
      
      Substance name in English AZODIISOBUTYRONITRILE
      
      Substance name in local language -
      
      Related Decree -
      
      Category PICCS
      
      Substance name in English PROPANENITRILE, 2,2'-AZOBIS(2-METHYL)
      
      Substance name in local language -
      
      Related Decree -
      
      Category PICCS
      
      Substance name in English Propanenitrile, 2,2'-azobis[2-methyl-
      
      Substance name in local language -
      
      Related Decree -
      
      Category PICCS
      
      Substance name in English PROPANENITRILE, 2-METHYL, 2,2'-AZOBIS
      
      Substance name in local language -
      
      Related Decree -

Chemical Hazard and Risk Information

Japan

GHS Classification Results by the Japanese Government
- NITE Japan-GHS Data Description GHS information
  - Edition version_1
    
    Chemical Substance Name 2,2'-Azobisisobutyronitrile
    
    Classification Result To the result webpage To the Excel flie
- GHS Classification Results by the Japanese Government Data Description GHS Information
  - Year of implementation /renewal 2006 ID 335_H18_new
    
    Chemical Substance Name 2,2'-Azobisisobutyronitrile
    
    Classification Result To the resut webpage To the Excel flie
    
    Year of implementation /renewal 2015 ID H27-B-02-METI/M-023B_P
    
    Chemical Substance Name 2,2'-Azobisisobutyronitrile
    
    Classification Result To the resut webpage To the Excel flie

Chemical Substances Hazard Assessment Report / Initial Risk Assessment Report

Chemical Substances Hazard Assessment Report / Initial Risk Assessment Report Data Description Guidance for Initial Risk Assessment ver.1 (in Japanese) Guidance for Initial Risk Assessment ver.2 (in Japanese)

Report Number	No.25
Assessed Chemical Substance Name	2,2'-Azobisisobutyronitrile
Details	Hazard Assessment Report (in Japanese)	Date of publication/ renewal	2006/10
	Details Initial Risk Assessment Report (in Japanese)	Date of publication/ renewal	2007/12
	Details Summary of Initial Risk Assessment Report	Date of publication/ renewal	2010/05

Synonym	2,2'-Azobis(2-methylpropanenitrile)
	2,2'-Azobisisobutyronitrile

Classification	I	Cabinet Order Number	1-16
Cabinet Order Name	2,2'-Azobisisobutyronitrile
Remarks	-
Basis of selection	Hazard Data (in Japanese)

Classification	Harmful Substances	Cabinet Order Number	Article 2-2 of Cabinet order
Cabinet Order Name	Cyanide compounds
Effluent Standards	1mg/L(CN)
Purification Standards	N.D.

Classification	Class 2	Cabinet Order Number	Article 1-5 of Cabinet order
Cabinet Order Name	Cyanide compounds
Soil Leachate Standard	N.D.(CN)
Soil Concentration Standard	50mg/kg(CN-)

Category	PICCS
Substance name in English	2,2'-AZOBIS(2-METHYL PROPANITRILE)
Substance name in local language	-
Related Decree	-

Edition	version_1
Chemical Substance Name	2,2'-Azobisisobutyronitrile
Classification Result	To the result webpage To the Excel flie

Year of implementation /renewal	2006	ID	335_H18_new
Chemical Substance Name	2,2'-Azobisisobutyronitrile
Classification Result	To the resut webpage To the Excel flie

Year of implementation /renewal	2015	ID	H27-B-02-METI/M-023B_P
Chemical Substance Name	2,2'-Azobisisobutyronitrile
Classification Result	To the resut webpage To the Excel flie